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J. Korean Ceram. Soc. > Volume 48(2); 2011 > Article
Journal of the Korean Ceramic Society 2011;48(2): 134.
doi: https://doi.org/10.4191/kcers.2011.48.2.134
Ni-doped Willemite계 청색안료에 관한 연구
이지연, 이현수1, 이병하
명지대학교 신소재공학과
1한양여자대학 도예과
A Study on the NiO-doped Willemite Pigments
Chi-Youn Lee, Hyun-Soo Lee1, Byung-Ha Lee
Department of Material Science & Engineering, Myongji University
1Department of Ceramic Art, Han Yang Women's University
To study the effect of color development of Ni-doped willemite blue pigments, five batches of compositions were prepared and fired at $1350^{circ}C$/hold for 1 h. When Ni was substituted for ZnO by 0.03 mole the optimum result were obtained. Then they were fired at $1300^{circ}C$ and held for 1, 2, 4 and 6 h respectively for the purpose sake. XRD, Raman spectroscopy, FT-IR, UV-vis were used to analyze the results of experiment. The substitution of 0.03mole Ni for Zn was most optimum and which produced good willemite at the temperature of $1300^{circ}C$, holding for 6 h. In ceramic arts, cobalt has been used for blue coloring, in most cases, despite of its high cost. If the low cost Ni-doped willemite blue pigments supplies for them with stable and multiple shades of blue pigment, using NiO at high temperature, it would provide various blues for ceramic wares.
Key words: Blue pigment, Ni-doped willemite pigment
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