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J. Korean Ceram. Soc. > Volume 51(5); 2014 > Article
Journal of the Korean Ceramic Society 2014;51(5): 424.
doi: https://doi.org/10.4191/kcers.2014.51.5.424
PVA 중합도가 고상-액상 혼합 방식에 의한 YAG:Ce3+ 형광체 분말 합성에 미치는 영향
김아름, 이상진
국립목포대학교 신소재공학과
Effect of PVA Polymerization on Synthesis of YAG:Ce3+ Phosphor Powders Prepared by a Solid-liquid Hybrid Route
A-Reum Kim, Sang-Jin Lee
Department of Advanced Materials Science and Engineering, Mokpo National University
ABSTRACT
YAG:$Ce^{3+}$ phosphor powders were synthesized using $Al(OH)_3$ seeds by means of a PVA-polymer-solution route. Various types of PVA with different molecular weights (different polymerization) were used. All dried precursor gels were calcined at $500^{circ}C$ and then heated at $1500^{circ}C$ in a mix of nitrogen and hydrogen gases. The final powders were characterized via XRD, SEM, PSA, PL, and PKG analyses. The phosphor properties and morphologies of the synthesized powders were dependent on the PVA type. As the molecular weight of the PVA was increased, the particle size gradually decreased with agglomeration, and the luminous intensity of the phosphor increased. However, the phosphor powder prepared from the PVA exhibiting very high molecular weight, showed a 531 nm (blue) shift from the 541 nm (yellow) wavelength of the YAG:$Ce^{3+}$ phosphor. Finally, the synthesized YAG:$Ce^{3+}$ phosphor powder prepared from the PVA with 89,000 - 98,000 molecular weight showed phosphor properties similar to those of a commercial phosphor powder, but without a post-treatment process.
Key words: Phosphor powder, PVA solution route, Molecular weight, Powder morphology, Phosphor property
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