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J. Korean Ceram. Soc. > Volume 61(6); 2024 > Article
Journal of the Korean Ceramic Society 2024;61(6): 1027-1035.
doi: https://doi.org/10.1007/s43207-024-00413-w
Research on anti-corrosion graphene coatings with promising properties
Hao-rui Yang1, Jie Chen1, Meng-Yuan Zhu1, Feng-Jun Zhang1,2, Qiang-fei Hu2, Won‑Chun Oh3
1Anhui Province International Research Center on Advanced Building Materials, Anhui Jianzhu University, Hefei, 230022, Anhui, People’s Republic of China
2Key Laboratory of Functional Molecule Design and Interface Process, Anhui Jianzhu University, Hefei, 230601, Anhui, People’s Republic of China
3Department of Advanced Materials Science and Engineering, Hanseo University, Seosan, 31962, South Korea
Correspondence  Qiang-fei Hu ,Email: huqf2019@163.com
Won‑Chun Oh ,Email: wc_oh@hanseo.ac.kr
Received: March 18, 2024; Revised: May 11, 2024   Accepted: May 25, 2024.  Published online: June 7, 2024.
*Hao-rui Yang and Jie Chen contributed equally to this work.
ABSTRACT
In order to investigate the effect of graphene content on coating properties, in the research, uniformly dispersed graphene powder was added to the epoxy resin system, preparing graphene coatings with high resistance to corrosion and decay. The diffraction peaks of the coating before and after immersing it in 3.5 wt% NaCl solution and the changes of its microstructure were compared by XRD and SEM, and the results showed the generation of a new composition Zn5(OH)8Cl2·H2O. At the same time, the experiments were carried out to analyze the anti-corrosion performance of the coatings in acid, alkali and salt environments by immersion method and electrochemical AC impedance test, etc. The analysis showed that the graphene coatings with the content of 0.125 wt% showed good anti-corrosion performance in 3.5 wt% NaCl, 2 mol/L HCl and 2 mol/L NaOH. The anti-corrosion properties may be due to the fact that graphene enhanced barrier character of the coating, slowing down the penetration of corrosive media, while the electrical conductivity of graphene is conducive to the zinc-rich coating sacrificial anode to achieve cathodic protection. This research provides a new solution for the production and application of industrialized graphene coatings.
Key words: Coatings · Anti-corrosion · Graphene · Epoxy resin
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