Hexagonal Boron Nitride의 합성에 있어서 MgB6 첨가의 효과 |
이대진, 지미정, 최병현, 이미재, 조남희1, 차미선2 |
요업.기술원 전자소재팀 1인하대학교 신소재공학부 반도성 재료연구실 2라지산업 |
Effect of MgB6 Addition on Synthesis of Hexagonal Boron Nitride |
Dae-Jin Lee, Mi-Jung Jee, Byung-Hyun Choi, Mi-Jai Lee, Nam-Hee Cho1, Mi-Sun Cha2 |
Electronic Materials Laboratory, Korea Institute of Ceramic Engineering & Technology 1School of Materials Science and Engineering, Inha University 2Large Industry |
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ABSTRACT |
The h-BN powder was synthesized by amorphous $B_2O_3$ and activated carbon at $1550^{circ}C$ in nitrogen atmosphere, whose properties were examined according to $MgB_6$ addition. Amount of $MgB_6$ addition was varied in the range of $0{sim}$10;wt% of the initial mixture. It was observed that $MgB_6$ addition led to an increase in the amount and the grain size of h-BN and decrease in the amount of $B_4C$ forming. When $MgB_6$ added 5 wt%, the amount and crystallinity of h-BN increased as the holding time at the synthesis temperature was prolonged. It was also confirmed that the regularity of three-dimensional ordering of h-BN increases. |
Key words:
Hexagonal boron nitride, Rhombohedral boron nitride, $MgB_6$, $B_4C$, Grain size |
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