초음파 분무 열분해법을 이용한 스칸디아 안정화 지르니코니아의 제조와 전기 전도도 |
최영훈, 백동현, 박영철, 임경태1, 서동수1, 서동수2, 서동수2 |
한국에너지기술연구원 수소.연료전지연구부 1충남대학교 나노공학부 |
Preparation and Electrical Conductivity of Scandia Stabilized Zirconia by using Ultrasonic Spray Pyrolysis |
Young-Hoon Choi, Dong-Hyun Peck, Young-Chul Park, Kyoung-Tae Lim1, Dong-Soo Suhr1, J. Wackerl2, T. Markus2 |
Korea Institute of Energy Research (KIER) 1Division of New Materials Engineering, Chungnam National University 2Institute of Energy Research(IEF-2), Research Centre Julich(FZJ) |
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ABSTRACT |
Scandia stabilized zirconia (ScSZ) is adapted for electrolyte material of solid oxide fuel cell (SOFC) because of its high ionic conductivity and chemical stability. ScMnSZ1 powder having a composition of $((ZrO_2)_{0.89}(Sc_2O_3)_{0.1}(MnO_2)_{0.01})$ is synthesized by ultrasonic spray pyrolysis (USP) method. Porous ScMnSZ1 powder is obtained by using a pore forming agent. Microstructure and morphology, particle size distribution of porous powder synthesized with 3wt% pore forming agent are investigated. Sintered ScMnSZ1 sample with ground fine powder are also investigated their microstructure and electrical conductivity. The electrical conductivity of sintered ScMnSZ1 samples with ground fine powder was 0.082 S/cm, 0.127 S/cm and 0.249 S/cm at $750^{circ}C$, $800^{circ}C$ and $900^{circ}C$, respectively. |
Key words:
ScSZ, SOFC, USP, Microstructure, Electrical conductivity |
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