결정화유리의 첨가에 의한 BNT계 세라믹스의 저온소결 및 마이크로파 유전특성 |
허동수, 이우석1, 정순종2, 송재성2, Futoshi Ustuno3, 류봉기 |
부산대학교 무기재료공학과 1부산대학교 무기재료공학 2한국전기연구원 전자기소자연구그 3일본 동경대학교 생산기술연구 |
Sintering and Dielectric Properties of BaO-Nd2O3-TiO2 Microwave Ceramics with Glass-Ceramics |
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ABSTRACT |
The microwave dielectric properties of low temperature sintered BaO-Nd$_2$O$_3$-TiO$_2$ (here after BNT) with a Pb-based glass-ceramics were studied in order to investigate their applicability to Low Temperature Co-fired Ceramics (LTCC) for fabrication of multilayered Radio Frequency (RF) passive components module. The BNT ceramics, with 5∼30 wt% of PbO-TiO$_2$-A1$_2$O$_3$-SiO$_2$ based glass-ceramics, were sintered at 105$0^{circ}C$, which is lower than 130$0^{circ}C$, sintering temperature of pure BNT ceramics. With increasing the amount of the glass-ceramics, sintering rate of the ceramics become activated due to the softening of glass, resulting in low-temperature densification. BaO-Nd$_2$O$_3$-TiO$_2$ microwave ceramics with 20 wt% glass-ceramics exhibit sintered relative densities over 95% and dielectric constant of 72, quality factor of 1500, and temperature coefficient of frequency of +22 ppm/$^{circ}C$. This enhanced dielectric properties are attributed to mainly the presence of crystalline phases PbTiO$_3$ within the Pb-based glass. |
Key words:
BaO-Ndsos-$TiO_2$, Glass-Ceramics, Low Temperature Co-Fired Ceramics (LTCC) |
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