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J. Korean Ceram. Soc. > Volume 39(2); 2002 > Article
Journal of the Korean Ceramic Society 2002;39(2): 184.
doi: https://doi.org/10.4191/kcers.2002.39.2.184
PDP Rib용 Bi2O3-B2O3-ZnO계 유리의 물성과 구조
진영훈, 전영욱, 이병철, 류봉기
부산대학교 무기재료공학과
Properties and Structures of Bi2O3-B2O3-ZnO Glasses for Application in Plasma Display Panels Rib
Young-Hun Jin, Young-Wook Jeon, Byung-Chul Lee, Bong-Ki Ryu
Department of Inorganic Materials Engineering, Pusan National University
ABSTRACT
This study, compared with data of PbO-base glass system is a part of new glass composition design with Bi-base composition for PDP Rib. As $Bi_2O_3-B_2O_3-ZnO$ glass composition including Bi, which have similar density value and work facility to PbO, properties of softening point, thermal expansion coefficient, chemical durability, dielectric constant, and structural changing by XPS were investigated. $Bi_2O_3-B_2O_3-ZnO$ glass system, added 50∼80 wt% $Bi_2O_3$ widely, were presented 400∼480$^{circ}C$ softening temperature, $68{sim}72{times}10^{-7}/^{circ}C$ thermal expansion coefficient and 13∼25 dielectric constant. These results were showed similar physical properties with Pb-base glass system of same composition content, application possibility as starting composition of rib material was identified through micro-control of components and physical properties. The bonding energy of $O_{1s}$ as the $Bi_2O_3$ content decreasing was increased and full width at half-maximum (FWHM) was decreased, which is caused by non-bridging oxygen increasing.
Key words: PDP rib, $Bi_2O_3-B_2O_3-ZnO$, Thermal and dielectric properties, XPS
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