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J. Korean Ceram. Soc. > Volume 34(4); 1997 > Article
Journal of the Korean Ceramic Society 1997;34(4): 420.
CuCl 미립자가 분산된 비선형 광학유리의 제조와 비선형 광특성: I. 제조와 미세조직 및 광특성
윤영권, 한원택
한국생산기술연구원
Preparation and Nonlinear Optical Properties of CuCl-doped Nonlinear Optical Glasses: I. Preparation, Microstructure, and Optical properties
ABSTRACT
Alumino-borosilicate glasses containing nano-sized CuCl crystals for nonlinear optical application were prepared by the melting and precipitation process, and structural and optical properties were investigated by using XRD, TEM, SAXS, and optical spectroscopy. the average radius of the precipitated CuCl particles was about 2 nm. The blue shift of Z3 resonance peak with decreasing the precipitated CuCl particles size was found and the radius increased with decreasing the glass transition temperature of the matrix glass and with increasing the temperature and duration time of the precipitation heat treatment.
Key words: CuCl, Semiconductor doped glass, Melting and precipitation method, nonlinear optics, nanocrystals
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