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J. Korean Ceram. Soc. > Volume 29(9); 1992 > Article
Journal of the Korean Ceramic Society 1992;29(9): 739.
기체분리용 세라믹 복합분리막의 개발: II. 극미세 입자 $TiO_2$ 졸의 제조 및 코팅 특성
현상훈, 박준수, 최세영
연세대학교 세라믹공학과
Development of Ceramic Composite Membranes for Gas Separation: II. Preparation and Coating Characteristics of Nanoparticulate $TiO_2$ Sols
The sols prepared by dialyzing solutions, in which the hydrolyzed precipitates of TEOT or directly Ti(OC3H7)4 were resolved, were the nanoparticulate sol with the average particle size less than 7 nm and the anatase crystal phase. In the pH range of 1.5 to 2.9, the particle size of the nanoparticulate TiO2 sols (0.09 mol/ι) increased gradually upto 15 nm~26nm with the increase of pH in the initial aging state but the sols were transparent all the time, and stable without growin any more after 30 days. When the slipcasted porous alumina tubes were coated by the sol-gel dipping method, the minimum particle size and the aging time for forming the coated gel layer at the given pH were optimized. For obtaining the very thin crack-free and reproducible membrane coating, the use of a nanoparticulate TiO2 sol (0.09 mol/ι) aged for about 30 dyas at pH=2.0 was found to be the best.
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