The Study on the Preparation of PSZ from the Domestic Zircon Sand its Applications I. Preparation of the High Purity Zirconia Powder form Domestic Zircon Sand

,; ,; ,; ,; ,; ,; ,; ,

J. Korean Ceram. Soc. > Volume 24(2); 1987 > Article

Journal of the Korean Ceramic Society 1987;24(2): 186.

국산 지르콘사로부터 부분 안정화 지르코니아의 제조 및 그 응용에 관한 연구 I. 국산 지르콘사로부터 고순도 지르코니아 분말의 제조

김환, 선우식, 신건철¹, 황규홍²

서울대학교 무기재료공학과
¹강원대학교 재료공학과
²경상대학교 재료공학과

The Study on the Preparation of PSZ from the Domestic Zircon Sand its Applications I. Preparation of the High Purity Zirconia Powder form Domestic Zircon Sand

ABSTRACT

ZrO2 powders having high purity were prepared from domestic zircon sand using the caustic fusion method and the soda ash sintering process. In the caustic fusion method, ZrO2 recovery was reached to 96% when 100/140 mesh zircon was reacted with NaOH at the NaOH/Zircon mole ratio 6 and at 650$^{circ}C$ for 2 hours. And in the soda ash sintering process, ZrO2 was recovered to 88.5% when -325 mesh zircon was reacted with Na2CO3 at the Na2CO3/Zircon mole ratio 1.1 and 1050$^{circ}C$ for 2 hours. In both cases, Zr component was extracted to ZrOCl2, subsequently crystallized to ZrOCl2$.$8H2O to increase the purity, and converted to ZrO2 by precipitation. And to increase the sinter ability of powder, Cl- ion was removed and strong agglomeration was avoided by methanol distribution of Zr(OH)4 precipitates.