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J. Korean Ceram. Soc. > Volume 20(3); 1983 > Article
Journal of the Korean Ceramic Society 1983;20(3): 236.
2가 금속산화물 첨가에 따른 납붕산염유리의 구조 및 물성
이찬수, 김철영
인하대학교 요업공학과
Structure and Properties in the $PbO-B_2O_3$ Glass System with Addition of Divalent Metallic Oxides
ABSTRACT
The purpose of present study is to find the structures physical properties and their inter-relations in the system of (60-x) PbO.xMO.$40B_2O_3$ glasses where MO represents for ZnO and CdO. The experiments such as differential thermal analysis infrared spectral analysis X-ray diffraction analysis density and thermal expansion measurements have been done. From infrared spectral analysis the structural units of glasses and the corresponding crystallized glasses were com-posed of $BO_3$ triangles and $BO_4$ tetrahedra. These basic units found in $PbO-B_2O_3$ binary glass system did not charge even though the divalent metallic oxides were substituted for PbO. The structures of these ternary glasses were more coalescenced than $PbO-B_2O_3$ binary glass system. This fact was supported bydecrease in thermal expansion coeffici-ent and molar volume with substitution of divalent metallic oxide for PbO. Crystalline phases obtained from the heat treatment of the $PbO-ZnO-B_2O_3$ glasses were 4PbO.2ZnO.$5B_2O_3$ PbO.2ZnO.$B_2O_3$ and unknown phases.
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