Adsorption of Ruthenium on the alkaline Earth Metal Compounds

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J. Korean Ceram. Soc. > Volume 19(2); 1982 > Article

Journal of the Korean Ceramic Society 1982;19(2): 145.

알카리토금속 화합물에 의한 루테늄의 흡착

류경옥, 문세기, 이근범

한양대학교 공과대학 화학공학과

Adsorption of Ruthenium on the alkaline Earth Metal Compounds

ABSTRACT

Many materials such as silica gel, metallic oxide, activated alumina and alkaline earth metal carbonates were employed as filter media for gaseous oxides of ruthenium volatilized during high level radioactive waste processing. The adsorption efficiency of ruthenium on these materials was evaluated. For the purpose of observing behavior of ruthenium oxides, thermogravimetric analysis of ruthenium oxide in a stream of oxygen was carried out. The rate of volatilization was proportional to the square root of oxygen partial pressure, and increased exponentially with temperature. At $650^{circ}C$, gaseous ruthenium oxides showed a strongly marked effect of deposition. Of all the materials available, calcium oxide proved to be the best that could be used to adsorb ruthenium.