| 투휘석-Devitrite계 복합용융체의 핵생성 및 결정성장의 최적화에 관한 연구 |
| 안영필, 오봉인1, 최롱2 |
한양대학교 무기재료과
1한양대학교 무기재료공학과
2쌍용중앙연구소 |
| A Study on the Optimization of Nucleation and Crystal Growth in Diopside-Devitrite System |
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| ABSTRACT |
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This study seeks to find optimum conditions for the heating schedule of the Diopside-Devitrite system, to find the amounts and the kinds of nucleus which effect the crystal growth and forming nucleus. Generally, crystallization in the glass depends on the number of nucleus growing in the internal system and the rate of crystal growth. In order to obtain homogeneous polystalline phae, Diopside as MgO source and $ZrO_2$.$P_2O_5$, $TiO_2$, NaF, $CaF_2$ as nucleating agents were added to the $Na_2O$.CaO.$6SiO_2$ glass. The results obtained were Summarized as follows. 1) Optimum Batch Composition of base glass is 76.82 wt.% $SiO_2$, 5.84 wt.% CaO, 4.54 wt.% MgO and 9.80 wt.% $Na_2O$. 2) Best heating schedule.140$0^{circ}C$(Melting)coolinglongrightarrow95$0^{circ}C$reheatinglongrightarrow$1100^{circ}C$coolinglongrightarrowRoom Temp. 3) The optimum amounts of $ZrO_2$.$P_2O_5$, $TiO_2$ and $CaF_2$ are 3wt.% and that of NaF is 4 wt.% as a nucleating agents. |
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