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J. Korean Ceram. Soc. > Volume 43(2); 2006 > Article
Journal of the Korean Ceramic Society 2006;43(2): 79.
doi: https://doi.org/10.4191/kcers.2006.43.2.079
증착온도를 달리하여 제조한 Zn0.8Co0.2O 박막의 미세조직 및 자기 특성
강영훈, 김봉석, 태원필1, 김기출2, 서수정, 박태석, 김용성
성균관대학교 정보통신용 신기능성 소재 및 공정연구센터
1울산산업진흥테크노파크 정밀화학센터
2한국전자통신연구소
Microstructure and Magnetic Properties of Pulsed DC Magnetron Sputtered Zn0.8Co0.2O Film Deposited at Various Substrate Temperatures
Young-Hun Kang, Bong-Seok Kim, Weon-Pil Tai1, Ki-Chul Kim2, Su-Jeung Suh, Tae-Seok Park, Young-Sung Kim
Advanced Material Process of Information Technology, Sungkyunkwan University
1Fine Chemical Industry Support Center, Ulsan Industry Promotion Techno Park
2Electronics and Telecommunications Research Institute
ABSTRACT
We studied the microstructure and magnetic property of the pulsed DC magnetron sputtered $Zn_{.8}Co_{0.2}O$ film as a function of substrate temperatures. The X-ray patterns of the $Zn_{.8}Co_{0.2}O$ film showed a strong (002) preferential orientation at $500^{circ}C$. The films with a crystallite size of 23-35 nm were grown in the form of nano-sized structure and this tendency was remarkable with increasing substrate temperature. The UV-visible result showed that the $Zn_{.8}Co_{0.2}O$ film prepared above $300^{circ}C$ has a high optical transmittance of over $80%$ in the visible region. The absorption bands were observed due to sp-d interchange action by $Co^{2+}$ complex ion and dd transition in the region from 500 to 700nm. The resistivity of the film was below $10^{-1};Omega-cm;above;300^{circ}C$. The AGM analysis results for the all films showed the magnetic hysteresis curves of ferromagnetic nature. The low electrical resistivity and room temperature ferromagnetism of ZnCoO thin films 'deposited above $300^{circ}C$ suggested the possibility for the application to Diluted Magnetic Semiconductors (DMSs).
Key words: ZnCoO thin films, Pulsed DC magnetron sputtering, Ferromagnetism, Diluted Magnetic Semiconductors (DMSs)
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