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J. Korean Ceram. Soc. > Volume 41(5); 2004 > Article
Journal of the Korean Ceramic Society 2004;41(5): 381.
doi: https://doi.org/10.4191/kcers.2004.41.5.381
조합화학을 이용한 (Gd0.74Y0.11Tb0.15P1.15)Oδ 형광체 합성 및 발광특성
이재문, 유정곤1, 박덕현1, 김지식2, 손기선
순천대학교 재료ㆍ금속공학과
1순천대학교 재료ㆍ금속공학
2상주대학교 신소재공학
Synthesis of (Gd0.74Y0.11Tb0.15P1.15)OδPhosphors Using Combinatorial Chemistry
ABSTRACT
Recently developed Plasma Display Panels (PDP) require phosphors of high luminance at Vacuum Ultraviolet (VUV) excitation. The present investigation developed new PDP phosphors using combinatorial chemistry method. We applied T $b^{3+}$ -activated yttrium gadolinium phosphates system to our combinatorial fine-tuning technique. As a result, the optimum composition was determined to be (G $d_{0.74}$ $Y_{0.11}$T $b_{0.15}$) $P_{1.15}$ $O_{delta}$ through the two-step combinatorial screening process including excess phosphorous and Gd replacement. We found that the sample of the optimum composition shows a higher luminescence efficiency at VUV excitation and a shorter decay time than the commercially available Z $n_2$ $SiO_4$:Mn phosphor.r.sphor.r.⠌㔀؀㘴ㄮ㔻᠀䡯浥…⁦慭楬礠浡湡来浥湴
Key words: Combinatorial ehemistry, VUV excitation, Excess Phosphorous, $YPO_4$$GdPO_4$
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