Preparation and Characterization of Stabilized <TEX>$ZrO_2$</TEX> by Wet Chemical Methods

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J. Korean Ceram. Soc. > Volume 16(3); 1979 > Article

Journal of the Korean Ceramic Society 1979;16(3): 155.

습식화학 방법에 의한 안정화된 $ZrO_2$의 제조 및 특성에 대한 연구

전승범, 변수일

한국과학원 재료공학과

Preparation and Characterization of Stabilized $ZrO_2$ by Wet Chemical Methods

ABSTRACT

This study was to explore the characteristics of 6 mole% CaO stabilized $ZrO_2$ prepared by wet chemical methods. The results of the experiments were as follows: 1. The powder calcined at 1000$^{circ}$-110$0^{circ}C$ was partly agglomerated. The morphology of agglomerate was spherical of 0.5-1$mu{m}$ in size for Hot Petroleum Drying Method, chain-like of 1-2$mu{m}$ for Freeze Drying Method, and irreqular of 2-3$mu{m}$ for Coprecipitation Method. 2. Optimum calcining conditions for powder prepared by wet chemical methods were found: 110$0^{circ}C$, 2h in air for Hot Petroleum Drying Method and Freeze Drying Method, and 100$0^{circ}C$, 2h in air for Coprecipitation Method. 3. When specimen was calcined at 1000$^{circ}$-110$0^{circ}C$ in air for 2h and then sintered at 1$600^{circ}C$ in air for 4h, the specimens prepared by wet chemical methods showed a high sintered density (94% of theoretical density) and a low open porosity (<0.8%); however, the sintered density of the specimen prepared by Oxide Wet Mixing Method was 90%. 4. The amount of cubic phase of sintered body prepared by wet chemical methods was observed to be higher than the one prepared by Oxide Wet Mixing Method. 5. It was found that Hot petroleum Drying Method, Freeze Drying Method and Coprecipitation Method were nearly the same in respect of the results of stabilization grade and sintered density of CaO-stabilized $ZrO_2$.